Case: 2 Aromatic Ring remains at fixed orientation with respect to the Lab. Fixed Axes system icon

Case: 2 Aromatic Ring remains at fixed orientation with respect to the Lab. Fixed Axes system

НазваниеCase: 2 Aromatic Ring remains at fixed orientation with respect to the Lab. Fixed Axes system
Дата конвертации21.10.2012
Размер10.14 Kb.
ТипДокументы

Aravamudhan, S. Dr. 10/14/12



Case: 2 Aromatic Ring remains at fixed orientation with respect to the Lab. Fixed Axes system




PROTON position changes in the molecule- fixed Coordinate axes








Magnetic Field Direction

(Is along the Laboratory Z-direction)








Z-Axis


Laboratory Fixed

Coordinate System

Y-Axis

X-Axis

ZM

YM

XM

ZM

XM

YM

ZM

YM

XM

Case:1 Proton position in the Lab. Fixed System is unaltered; the aromatic ring changes orientation in Lab frame of reference. Obviously, the angle of the proton position vector with respect to the molecular symmetry axis ( ZM ) varies. This makes the conventional equations (used for isotropic ring current shifts) not applicable.




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